全文获取类型
收费全文 | 4458篇 |
免费 | 727篇 |
国内免费 | 490篇 |
专业分类
化学 | 1171篇 |
晶体学 | 69篇 |
力学 | 969篇 |
综合类 | 104篇 |
数学 | 1329篇 |
物理学 | 2033篇 |
出版年
2024年 | 8篇 |
2023年 | 36篇 |
2022年 | 68篇 |
2021年 | 77篇 |
2020年 | 112篇 |
2019年 | 98篇 |
2018年 | 98篇 |
2017年 | 156篇 |
2016年 | 167篇 |
2015年 | 136篇 |
2014年 | 213篇 |
2013年 | 379篇 |
2012年 | 250篇 |
2011年 | 313篇 |
2010年 | 221篇 |
2009年 | 287篇 |
2008年 | 262篇 |
2007年 | 295篇 |
2006年 | 266篇 |
2005年 | 217篇 |
2004年 | 229篇 |
2003年 | 230篇 |
2002年 | 200篇 |
2001年 | 156篇 |
2000年 | 150篇 |
1999年 | 157篇 |
1998年 | 124篇 |
1997年 | 84篇 |
1996年 | 92篇 |
1995年 | 88篇 |
1994年 | 76篇 |
1993年 | 68篇 |
1992年 | 63篇 |
1991年 | 46篇 |
1990年 | 41篇 |
1989年 | 33篇 |
1988年 | 29篇 |
1987年 | 26篇 |
1986年 | 16篇 |
1985年 | 21篇 |
1984年 | 15篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 7篇 |
1957年 | 3篇 |
排序方式: 共有5675条查询结果,搜索用时 15 毫秒
111.
Feding Ge Jing Zhu Limin Chen 《International Journal of Infrared and Millimeter Waves》1996,17(2):449-455
The effective parameters of chiral composite are studied using a simple model, that is, randomly oriented non-interacting wire helices embedded in a nonchiral host medium. It is found that both the effective permittivity and permeability are independent on the handedness of the chiral objects while the effective chirality admittance is dependent. It is also found that when the ratio of the radius of the chiral helix to its pitch is about 0.23, maximum chirality admittance is achieved. The effective parameters of equichiral sample are also discussed. 相似文献
112.
Jeffrey Bub 《Foundations of Physics Letters》1993,6(1):21-35
Elby (1993) has raised certain problems that appear to be devastating for modal interpretations of quantum mechanics, but do not arise for Bohm's pilot wave theory. Here I show that the features Elby identifies as objectionable in my version of the modal interpretation have their counterpart in Bohm's theory. To the extent that Bohm's theory works as a no collapse solution to the measurement problem - and I think it does - so does my modal interpretation. 相似文献
113.
Numerical simulations are done of Langevin dynamics for a uniform-orderparameter, field-swept Landau model,= –|a/2|m
2+|b/4|m
4–mh(t) , to study hysteresis effects. The field is swept at a constant rateh(t)=h(0)+ht. The stochastic jump values of the field {hJ from an initially prepared metastable minimumm(0) are recorded, on passage to a global minimum m(). The results are: (a) The mean jump¯h
J(h) increases (hysteresis loop widens) with h, confirming a previous theoretical criterion based on rate competition between field-sweep and inverse mean first-passage time (FPT); (b) The broad jump distribution(h
J,h) is related to intrinsically large FPT fluctuations (
2–2)/
2 O(1), and can be quantitatively understood. Possible experimental tests of the ideas are indicated. 相似文献
114.
自Hansch等创立QSAR法以来,药物构效关系的研究已获得较大的进展。本文将模式识别法用于芬太尼衍生物构效关系的研究,将该类药物的分子结构看作与生物活性具有对应关系的表现形式——模式,以药物分子结构中有关取代基的多个量子化学参数为数量化的模式向量成分。将已知生物活性的药物作为模式识别训练点,则所得模式识别分类图反映了该类药物的生物活性与其量子化学结构特征参数间的统计学意义的关系。它既可用来探寻高效药物的结构参数,又能预测新设计药物生物活性的等级或类别。 相似文献
115.
Karen?Glenn Andrew?van?Bommel Subhash?C.?Bhattacharya Rama?M.?PalepuEmail author 《Colloid and polymer science》2005,283(8):845-853
The mixed micelles of sodium dodecyl sulphate (SDS) with Brij35 and Brij 97 were studied separately by fluorescence measurement using pyrene as fluorescent probe. In the range of 0–1.0 mole fraction (X) of added SDS to Brij solutions, the cmc value of the mixed micelles varies from 0.085 to 8 mmol with Brij 35 and 0.04 to 8 mmol with Brij 97. The aggregation number also changes. A measure of the stability of mixed micelles is also presented. The interaction parameter 12 and the chain–chain contribution parameter (B1) are extracted from the analysis of the results. This parameter B1 is related to the standard free energy change associated with the introduction of one ionic species into a nonionic micelle coupled with the release of one nonionic species from the micelle. The clouding behaviour of Brij 97 in the presence of SDS was investigated and the associated thermodynamic parameters of clouding were generated and discussed. 相似文献
116.
ZHUO Ke-Lei WANG Jian-Ji LIU Wen-Bin LU Jin-SuoDepartment of Chemistry Henan Normal University Xinxiang Henan China 《中国化学》1996,(3)
Pt,H2(g,p0)HCl(mE)|AgCl-AgPt, H2(g, p0)|HCl(mE), EtOH(mN)|AgCl-Ag have been measured at 10 degree intervals from 278.15 to 318.15 K, where EtOH refers to ethanol, mE=0.005-0.1 mol.kg-1, mN=0.4-1.0 mol.kg-1. The salting constant kS of EtOH by HCl and the thermodynamic parameters of interaction, fEN(gEN> hEN, sEN] cP,EN)> of EtOH with HCI in water have been evaluated. It has been shown that kS>0, gEN>0,hEN>0, SEN>0 ,and cp,EN<0.The signs of these parameters and the temperature dependence of them have been discussed on the basis of structural interaction and the group additivity models. 相似文献
117.
方俊 《中国科学B辑(英文版)》1991,(1)
In the linear inversion of the radial variation of the parameters of the Earth by usingthe observed frequencies of various normal modes of free oscillation of the earth, it is neces-sary to know the values of the kernels of the parameters ρ, μ and λ. This paper describesthe methods of the derivation of the formulas of these kernels. This is the first part of thepaper in which only the toroidal oscillations are considered. They are much simpler thanthose of the spheroidal ones, that we will consider in the second part of the paper. The data of the two types of oscillations are equally important in the solution of theinversion problem, and should be employed simultaneously, and we know that the toroidaloscillations are much simpler than the spheroidal ones, it seems wise to divide the whole programof the inversion problem into steps: first, by employing the toroidal data to correct the twoparameters ρ and μ in the mantle, then by using the spheroidal data to correct the remain-ing parameters, i.e. th 相似文献
118.
本文研究了聚(ε-己内酯)(PCL)在其与苯乙烯-丙烯腈共聚物(SAN)的相容共混物中球晶生长速率与共混组成和结晶温度的关系.发现聚己内酯的球晶生长速率随着SAN的含量增加而下降.由于PCL与SAN是相容共混物,因此在用二次成核动力学方程描述PCL球晶生长速率时,我们引进了相互作用参数X.结果由共混体系的结晶动力学方程计算到的X值与由平衡熔点下降方法计算到的X_(23)值是相同的;而PCL晶体的折叠表面自由能则随着SAN含量的增加而下降.这些结果说明非晶高聚物SAN有碍于PCL球晶的生长. 相似文献
119.
120.